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Nitride fluoride

Last updated: 2025-07-23 06:08:09

Nitride fluoride

Nitride fluorides containing nitride and fluoride ions with the formula NF4-. They can be electronically equivalent to a pair of oxide ions O24-. Nitride fluorides were discovered in 1996 by Lavalle et al. They heated diammonium technetium hexafluoride to 300 °C to yield TcNF.[1] Another preparation is to heat a fluoride compound with a nitride compound in a solid state reaction.[2] The fluorimido ion is F-N2- and is found in a rhenium compound.[3]

nameformulaN:F ratiosystemspace groupunit cell (Å)volumedensitypropertiesreferences
dimagnesium fluoride nitrideL-Mg2NF1:1tetragonalI41/amda = 4.186, c = 10.042decompose over 1000 °C to MgF2, Mg gas and N2[1][4]
H-Mg2NF1:1H for 1250-1350 °C and 20 kbar[1][4]
Mg3NF31:3cubicPm3ma = 4.216light green[1][4]
dicalcium fluoride nitrideCa2NF1:1cubicFd3ma = 10.0215, Z = 161006.462.987light yellow[1]
dichromium fluoride nitrideCr2NF31:3dark green[5]
dicobalt fluoride nitrideCo2NF1:1[1]
dicopper fluoride nitrideCu2NF1:1[1]
CaMgNF1:1[1]
Fe4N3F31:1[6]
αZn2NF1:1orthorhombicP212121a = 5.850, b = 5.892, c = 6.536band gap 2.7 eV[1]
βtetragonalP41212a = 5.873, c = 6.532band gap 2.8 eV
Zn9N4F62:32 allotropes[1]
Zn7N4F4:1[1]
distrontium fluoride nitrideSr2NF1:1Fd3ma = 10.692, Z = 16yellowish brown[1][7]
Fd3ma = 10.765, Z = 16dark red[7]
SrCaNF1:1cubicFd3ma = 10.340, Z = 161105.63.862yellow[8]
YNF31:3hexagonala = 5.93, c = 4.79[9]
Zr4ON3F53:5monoclinicP1121/ba = 5.1217, b = 21.513, c = 5.3669, γ = 90.128°, Z = 4
ZrNF1:1monoclinicP21/ca = 5.227, b = 5.026, c = 5.191, β = 98.98°[1]
NaZr3N3F43:4P63/mmca = 3.654, c = 18.266[10]
TcNF1:1hexagonala = 5.98, c = 4.79[1]
dibarium fluoride nitrideBa2NF1:1Fm3ma = 5.679, Z = 2dark violet[11]
LaNxF3(1-x}x:3(1-x}cubica = 5.847–5.871[1]
Ce3NF61:6a = 5.8027F− conductor[12][2]
Pr3NF61:6a = 5.7723[12]
Gd3NF61:6cubica = 5.617[1]
Ce2MnN3F2−δtetragonalP4/nmma = 3.8554, c = 13.088Nitridomanganate[13]
LiSr2[TaN3]F3:1orthorhombicPbcaa = 10.768, b = 5.591, c = 15.891, Z 8956.7Nitridotantalate, red, air sensitive[14]
ReNF1:1tetragonala = 5.88, c = 13.00[1]
Bi3NF61:6orthorhombicPbcma = 5.8174, b = 5.7018, c = 18.5113, Z = 4614.018.165grey, moisture sensitive[15]
ThNF1:1rhombohedrala = 7.13[1]
ThNxF4-3xtetragonal[1]
UNxFy (UNF)1:1orthorhombica = 5.632–5.643, b = 5.602–5.610, c = 5.712–5.707[1]
Complexes
(AsPh+
4)2[O2(TcNF2)2]2-		1:2yellow, O-bridged[16]
Rb4[O(TcNF4)2]1:4orange yellow[16]
Cs4[O(TcNF4)2]1:4orange yellow[16]
H[TcNF4]1:4[16]
(NEt4)3(NH4)[Tc4N4O4F8]yellow green[16]
molecules
phosphonitrile fluoride (trimer)(NPF2)31:2rhombohedraltriple point 27.8 °C; refractive index nα = 1.388, nβ = 1.419, nγ = 1.443[17][18]
phosphonitrile fluoride (tetramer)(NPF2)41:2monoclinictriple point 30.5 °C[17]
poly-phosphonitrile fluoride(NPF2)n1:2[17]
ReNF31:3brown[19]
rhenium tetrafluoride nitrideReNF41:4orthorhombica = 5.64, b = 14.76, c = 4.26354.6yellow, molecular, mp 85 °C[19]
fluoroimidorhenium pentafluorideReNF61:6monoclinica = 5.298, b = 9.286, c = 9.979, β = 109.4, Z = 4463.24.507orange, molecular, N-F bonded, mp 80 °C[19]

References

  1. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Al-Azzawi, Mohanad A. (2016). Synthesis and Characterization of Single Crystalline Metal Nitride Fluorides (Thesis). Youngstown State University.
  2. 1 2 Noetzel, Gerd; Schweda, Eberhard; Wiemhöfer, Hans-Dieter (February 2010). "Ionic Conductivity of Ce3NF6". Zeitschrift für anorganische und allgemeine Chemie. 636 (2): 389–394. doi:10.1002/zaac.200900472.
  3. ↑ Dehnicke, Kurt.; Straehle, Joachim. (May 1993). "N-Halogenoimido complexes of transition metals". Chemical Reviews. 93 (3): 981–994. doi:10.1021/cr00019a007. ISSN 0009-2665.
  4. 1 2 3 Andersson, Sten (April 1970). "Magnesium nitride fluorides". Journal of Solid State Chemistry. 1 (3–4): 306–309. Bibcode:1970JSSCh...1..306A. doi:10.1016/0022-4596(70)90109-X.
  5. ↑ Westland, Alan D. (February 1973). "The reaction of chromium(II) fluoride with nitrogen". Journal of Inorganic and Nuclear Chemistry. 35 (2): 451–456. doi:10.1016/0022-1902(73)80556-1.
  6. ↑ Day, P. (1977). Electronic Structure and Magnetism of Inorganic Compounds. Royal Society of Chemistry. p. 127. ISBN 978-0-85186-291-0.
  7. 1 2 Wagner, T.R. (November 2002). "Preparation and single-crystal structure analysis of Sr2NF". Journal of Solid State Chemistry. 169 (1): 13–18. Bibcode:2002JSSCh.169...13W. doi:10.1016/S0022-4596(02)00002-6.
  8. ↑ Keino, Oscar Kipruto (December 2017). "Investigations of Mixed-Anion Analogs of Manganite Perovskites and Bimetallic Group II Nitride Fluorides".
  9. ↑ Ashcraft, Richard Henry (1982). PREPARATION OF NEW METAL NITRIDE-FLUORIDES AND OTHER HIGH-TEMPERATURE STUDIES (Thesis thesis). hdl:1911/15665.
  10. ↑ Stoltz, C.; Ramesha, K.; Piccoli, P.; Toby, B. H.; Eichhorn, B. W. (October 2005). "A 0.3 ZrNF 1.3 Phases (A = Na, K) with Layered ZrNCl-Type Structures Prepared by Anion Metathesis". Chemistry of Materials. 17 (21): 5291–5296. doi:10.1021/cm051018h. ISSN 0897-4756.
  11. ↑ Seibel, H; Wagner, T.R (August 2004). "Preparation and crystal structure of Ba2NF". Journal of Solid State Chemistry. 177 (8): 2772–2776. Bibcode:2004JSSCh.177.2772S. doi:10.1016/j.jssc.2004.04.026.
  12. 1 2 Vogt, T.; Schweda, E.; Laval, J.P.; Frit, B. (December 1989). "Neutron powder investigation of praseodymium and cerium nitride fluoride solid solutions". Journal of Solid State Chemistry. 83 (2): 324–331. Bibcode:1989JSSCh..83..324V. doi:10.1016/0022-4596(89)90182-5.
  13. ↑ Headspith, David A.; Sullivan, Eirin; Greaves, Colin; Francesconi, M. Grazia (2009). "Synthesis and characterisation of the quaternary nitride-fluoride Ce2MnN3F2−δ". Dalton Transactions (42): 9273–9. doi:10.1039/b908591b. ISSN 1477-9226. PMID 20449206.
  14. ↑ Pust, Philipp; Schnick, Wolfgang (September 2011). "LiSr2[TaN3]F – a Single Chain Nitridotantalate". Zeitschrift für anorganische und allgemeine Chemie. 637 (11): 1486–1489. doi:10.1002/zaac.201100207.
  15. ↑ Hofmann, M.; Schweda, E.; Strähle, J.; Laval, J.P.; Frit, B.; Estermann, M.A. (January 1995). "Synthesis and Structure of Bi3NF6: A Member with n = 3 of the Vernier Phases MnX2n+1". Journal of Solid State Chemistry. 114 (1): 73–78. Bibcode:1995JSSCh.114...73H. doi:10.1006/jssc.1995.1011.
  16. 1 2 3 4 5 Balasekaran, Samundeeswari Mariappan (July 2013). "Fluorido complexes of Technetium". Freie Universität Berlin.
  17. 1 2 3 Seel, F.; Langer, J. (July 1958). "Über Phosphornitrilfluoride. I". Zeitschrift für anorganische und allgemeine Chemie (in German). 295 (5–6): 316–326. doi:10.1002/zaac.19582950506. ISSN 0044-2313.
  18. ↑ Jagodzinski, H.; Langer, J.; Oppermann, I.; Seel, F. (November 1959). "Über Phosphornitrilfluoride. II. Zur Struktur und Kristallographie der Phosphornitrilfluoride". Zeitschrift für anorganische und allgemeine Chemie (in German). 302 (1–2): 81–87. doi:10.1002/zaac.19593020108. ISSN 0044-2313.
  19. 1 2 3 Fawcett, John; Peacock, Raymond D.; Russell, David R. (1987). "Preparation of the nitrenes ReF5(NF), ReF5(NCl), and ReF5(NBr). X-Ray crystal structures of ReF5(NF) and ReF5(NCl)". Journal of the Chemical Society, Dalton Transactions (3): 567–571. doi:10.1039/dt9870000567. ISSN 0300-9246.


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